After bagging the title as the first "Grand Teen Questor" of ABS-CBN's Star Circle Quest, Hero appeared in several TV shows in the network like the youth oriented program SCQ Reload and was also one of the casts of the fantasy series Krystala, lead by Judy Ann Santos. He was one of the hottest young star in 2004, and his team-up with Sandara Park was so popular then making box-office movies like Bcuz Of U and Can This Be Love.

In 2005, Hero ended his contract with ABS-CBN Star Magic, which was controversial, and later on he was seen appearing in various TV shows on ABS-CBN's rival network, GMA-7. Then as of March 2008, Angeles is under the network contract of GMA Network with the management of German Moreno and brother Henry Angeles. His first break is playing the role of Mark in Dyesebel which stars Marian Rivera and Dingdong Dantes. After Dyesebel, he plays one of the main villains in Luna Mystika, which stars his fellow former Kapamilya star Heart Evangelista and Mark Anthony Fernandez.

Angeles also made his first directorial job in 2007 entitled Stockroom blending modern scares with social issues on employment of language teachers in the Philippines. It went sold-out for its Cinemalaya Philippine Independent Film Festival. The film also had its World Premiere at the prestigious St. James Cavalier Theatre in Valletta, Malta in Europe last November 2007. After joining Luna Mystika Angeles will join the first Sine Novela of Jennylyn Mercado and Mark Herras that entitled Sine Novela: Paano Ba Ang Mangarap?.

Since year 2006. Angeles has been a regular co-host with German 'Kuya Germs' Moreno in the Saturday late night show "Walang Tulugan with the Master Showman" which is very popular among Filipino communities abroad. Shown through GMA and GMA Pinoy TV.

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